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The song was co-written and recorded by the country singer for the upcoming comedy after Witherspoon personally asked her.
While Witherspoon perfectly mouths every word to 'I Knew You Were Trouble' and 'Party in the U.S.A.', her 'Hot Pursuit' co-star sings with a man's voice.
Sofia Vergara's bombshell character looks horrified when finding out that her runaway pal reveals plain white underwear underneath her police uniform.
The 'Hot Pursuit' beauty will be joined by Florence and the Machine as musical guest on May 9, while the 'Louie' star will host the May 16 episode with Rihanna as musical guest.
Lambert, Kellie Pickler and Jamie Lynn Spears show some skin in their gowns, while Witherspoon and her 'Hot Pursuit' co-star Sofia Vergara wear matching sparkling dresses.
The song titled 'Two of a Crime' which is expected to have a 'Southern and a Latin flavor' will be released on April 28, a week before the film opens in theaters on May 8.
Witherspoon credits Holly Hunter, Sigourney Weaver, and Debra Winger as strong women who become her role models.
The 'Wild' actress puts on a wig to disguise herself as a teen heartthrob as she is on the run from criminals and corrupted cops.
The 'Wild' actress basks in the sun in a donut-shaped pool float and then shares the photo on Twitter.
The birthday girl received best wishes from fellow celebrities, like Ellen DeGeneres and Sofia Vergara, in addition to Vogue Magazine.
Witherspoon, who is a police officer, is protecting a drug dealer's wife played by Vergara, resulting in hilarious adventure.
Amy donned a white figure-hugging, floor-length gown, Reese flaunted her cleavage in a plunging purple long dress with a little train, while Felicity wore a black and lilac dress.
In addition to the threesome, Marion Cotillard and Meryl Streep have also been tapped as additional award presenters for the annual ceremony set to take place on Sunday, February 22.
Other celebrities who are also featured in the magazine include Benedict Cumberbatch, Eddie Redmayne, Felicity Jones, David Oyelowo, Sienna Miller, Oscar Isaac and Miles Teller.
Oprah looked fabulous in her knee-length purple dress, Reese sported a monochrome sleeveless gown, while Emma paired a striped top with a polka mid-length skirt.