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The 'Girl on Fire' singer is expected to set the court ablaze with her impeccable live performance.
Keys sings the national anthem 'Star-Spanled Banner' before the game, while Hudson delivers a touching rendition of 'America the Beautiful' with Sandy Hook Elementary School Chorus.
After rocking the 5,000 plus crowd at their Los Angeles, Grohl and his star-studded Sound City group are scheduled to perform in New York.
Refaeli and Jesse Heiman need 65 takes to get the saucy scene right, only to get it cut off for being too intense.
Whitney collects Best Song and Best Album, Alicia scoops Best Female Artist and Best Music Video, while Usher is awarded Best Male Artist.
The video shows a number of dancers rehearsing some fierce moves while 'Countdown' is played in the background.
The addition of the three musical acts confirms that the 55th annual Grammy Awards will feature performances by all five nominees for Album of the Year and three on-stage collaborations.
Keys rocks the president's official inaugural ball in Washington D.C. on January 21 with her renditions of 'New Day' and 'Girl on Fire', while Hudson sings 'Let's Stay Together'.
It will be the 'Girl on Fire' singer's third appearance at the annual championship game of the NFL.
The 'Girl on Fire' hitmaker will go on a North American concert tour with neo-soul artist Miguel.
Other performers at the 39th annual People's Choice Awards at the Nokia Theatre in Los Angeles include Jason Aldean and Taylor Swift.
The 'A Woman's Worth' hitmaker is being sued by songwriter Earl Shuman for copyright infringement over her hit 'Girl on Fire'.
Vying for the top Best Picture award, the history movie shatters the record for a film with the most nominations previously held by 'Black Swan' in 2010.
Keys and Mars are among the nominees for music in the 44th annual National Association for the Advancement of Colored People Image Awards to be held on February 1, 2013.
Keys lands atop of the Billboard 200 chart for the fifth time in her career while Rihanna slips below the top 5 this week.