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The country music veterans get seven nominations apiece while Keith Urban follows closely behind with six.
The 'Come and Get It' singer is reportedly seeing the younger man after a matchmaking effort from Taylor Swift.
Katy wears a unique dress with note-printed skirt, Chrissy and Taylor stun in gleaming gowns, while Colbie Caillat and Paris Hilton show some skin in their red and white gown respectively.
In addition to performing, McCartney and fellow former member of The Beatles Ringo Starr will accept the 2014 Recording Academy Lifetime Achievement Award.
Other beauties that stole the night were Amy Adams, Sofia Vergara, Cate Blanchett, and pregnant stars Kerry Washington and Olivia Wilde.
The British singer says that he wants to surprise people with his upcoming album and explains that another collaboration with the 'Red' hitmaker won't be shocking.
Swift tops the list of DoSomething.org's most charitable celebrities of 2013 with her various contributions to people in need, while Harry Styles and his bandmates are in second place.
The 'Sweeter Than Fiction' singer says that the follow-up to Grammy Awards-nominated 'Red' album will feature songs about her stories.
The late actors joined iPhone 5, Royal Baby and North Korea among others in the top 10 most searched terms of 2013.
The 'Royals' hitmaker sings live from Los Angeles, while the 'I Knew You Were Trouble' singer performs from Australia.
'She's heard all the songs and she's a good judge of what's good or not good,' the 'Lego House' singer says of seeking the country star's approval.
The Duke of Cambridge accepts Bon Jovi's invitation to perform 'Livin' on a Prayer' together onstage after asking Swift to accompany him.
Swift also bags awards for Favorite Female Artist in Pop/Rock and Country categories, making her one of the big winners besides Justin Timberlake and One Direction at the event.
The 'Mirrors' singer nabs the first award of the night, Favorite Male Artist in Pop/Rock, while the Bajan beauty is named Favorite Soul/R&B Female Artist.
A representative of the 'I Knew You Were Trouble' singer said they only heard about the incident after officials reached out to her.