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The British R 'n' B songstress reminds herself that she has a 'Wonderful Life' in the sunny and happy video.
Estelle is moving on from a bad relationship, while Santigold includes footage which raises speculation that she mocks Lady GaGa and Katy Perry.
The fresh video, which is taken during the re-shoot of the superhero film in New York, gives a look at a web-slinging action scene of a stuntman who dons an early Spider-Man costume.
The other newly-revealed performers are Marsha Ambrosius, Boyz II Men, Travis McCoy, Sharon Jones and The Dap-Kings.
The 'American Boy' hitmaker would rather rekindle the old romance than go to find a new one.
'I'm thinking about him, but in my heart I'm doubting, maybe he'll break my heart,' the 'American Boy' singer says of her scene in the music video.
In a music video for the Janis Joplin remix track, Estelle, Daley and David Banner spend a 'groovy' night together in their apartment.