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The British R 'n' B songstress reminds herself that she has a 'Wonderful Life' in the sunny and happy video.
Estelle is moving on from a bad relationship, while Santigold includes footage which raises speculation that she mocks Lady GaGa and Katy Perry.
The fresh video, which is taken during the re-shoot of the superhero film in New York, gives a look at a web-slinging action scene of a stuntman who dons an early Spider-Man costume.
The other newly-revealed performers are Marsha Ambrosius, Boyz II Men, Travis McCoy, Sharon Jones and The Dap-Kings.
The 'American Boy' hitmaker would rather rekindle the old romance than go to find a new one.
'I'm thinking about him, but in my heart I'm doubting, maybe he'll break my heart,' the 'American Boy' singer says of her scene in the music video.
In a music video for the Janis Joplin remix track, Estelle, Daley and David Banner spend a 'groovy' night together in their apartment.
Both featuring Jesse Williams as Estelle's love interest, the music videos have additional cameos from John Legend in one of them and Nas in the other.