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Musgraves gives the first TV performance of the song, which is not included in her Grammy-winning album 'Same Trailer Different Park'.
Plunging neck dresses that showed off cleavage were particularly popular among the female attendees of the April 6 event.
The country music veterans get seven nominations apiece while Keith Urban follows closely behind with six.
The two young artists received six nods apiece, going head to head for Female Vocalist and Album of the Year.
One of the new emerging singers in country music that people are going to hear a lot is the 'Merry Go 'Round' crooner.