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Perry will open this year's show with new single 'Unconditionally', while Lopez is set to perform a tribute to the late music legend Celia Cruz
The music video for the Ne-Yo-penned track features TLC's members reuniting in a recording studio.
The Ne-Yo-penned track, which will be featured in TLC's upcoming greatest hits album, also serves as the soundtrack to their VH1 biopic that will premiere on October 21.
The new greatest hits album will feature TLC's greatest hits, including 'No Scrubs', 'Waterfalls', 'Unpretty' and 'Creep', as well as Ne-Yo-penned new track called 'Meant to Be'.
Lisa 'Left Eye' Lopes' relationship with NFL player Andre Rison is featured briefly in the promo video.
The rapstress, who plays Left Eye in the group's VH1 biopic, joined T-Boz and Chilli onstage last Saturday, July 27.
In the promo for the biopic, Keke Palmer, Drew Sidora and Lil' Mama recreate some of the R'n'B/hip-hop/pop group's music videos.
The two surviving members of the group have worked with Ne-Yo, Lady GaGa and Dallas Austin for the yet-to-be-titled album, which will feature guest appearances from Drake and J. Cole.
Surviving members T-Boz and Chilli say they were blocked from using Left Eye's original rap in the remake.
Tionne Watkins and Rozanda Thomas disappoint Lisa Lopes' family when they hire Japanese singer Namie Amuro to fill in for the late group member for a remake version of the 1995 hit.
Sculptors are preparing the wax statue of the 'Someone Like You' singer and it is planned to be unveiled in July.
The former Nickelodeon star posts a picture of her wearing a blonde-green wig while showing off her cleavage in a rolled-up shirt.
Palmer, Sidora and Mama play Rozonda 'Chilli' Thomas, Tionne 'T-Boz' Watkins and Lisa 'Left Eye' Lopes respectively in the upcoming TV movie about the R'n'B/hip-hop/pop group.
The surviving members of the '90s girl group will reunite to join boybands New Kids On The Block and Jonas Brothers for the Pennsylvania music fest.
The surviving members of the 90s hip hop group confirm they are planning to create their first album ten years after the passing of third member Lisa 'Left Eye' Lopes.