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The trailer assembles Spidey's toughest enemies, while the featurette gives a first look at Felicity Jones.
The villain who is also known as Herman Schultz escapes from Ryker's Island just before the scheduled start of his trial.
Also featuring contributions from Pharrell Williams and Hans Zimmer, the track called 'It's On Again' will appear in the soundtrack album that arrives on April 22.
One video sees Peter Parker and Gwen Stacy kissing in a closet-like place, while the other footage shows Electro lashing out at a sniper.
The new sneak-peek video shares more scenes from the fight between the webslinger and Jamie Foxx's Electro.
The new picture teases a fight scene between Spidey and Harry Osborn's villainous alter ego inside a giant clock.
The Spider-Man co-creator is seen sitting among the attendees at Peter Parker and Gwen Stacy's high school graduation.
The Ultimate Spider-Slayer is promoted to become the Director of Robotics, a position previously held by his father at the Oscorp.
Marc Webb says the 'Saving Mr. Banks' actor will play a character who would later become the Ultimate Spider-Slayer.
The enemies unite in an extended trailer, and Spider-Man tries to save Gwen Stacy in the new Super Bowl ad.
The promotional spot prompts question whether the film will stay close to the comic book when it comes to Emma Stone's character.
Electro sends people at the crowded NYC epicenter into panic before Spider-Man swings by to handle the troublemaker.