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In the Halloween episode, Rihanna is playing bank robber Clyde with Andy Samberg as shy Ronnie while Hamm is their hostage.
Accompanied by Kenan Thompson, the actor makes his companion nervous, angry and surprised in the three separate promos.
Because 'very few customers abroad ever get quality time with those in front or behind the camera,' the event is held so that the stars can talk about the show to international buyers.
The Don Draper of 'Mad Men' has no respect to reality show stars out there, branding them as people with 'zero dignity'.
'I did do therapy and antidepressants for a brief period, which helped me,' the 'Mad Men' star recalled the time he became an orphan at the age of 20.
Beside stating that he hasn't been approached by movie bosses about the part, the 'Mad Men' actor believes he 'maybe aged out of that competition.'
The on-screen couple was joined by co-stars Jon Hamm and Jeremy Renner at the Wednesday, September 8 event which took place at Palazzo del Cinema.
In an effort to raise money for tickets to attend Emmys, Tina Fey, Jane Lynch, Jorge Garcia, Nina Dobrev, Joel McHale and Jon Hamm agree to join Jimmy Fallon's crew.
Sources reveal that Warner Brothers and Legendary Pictures have their eyes on the 39-year-old actor to play Clark Kent in 'The Man of Steel'.
Despite its generally large ensemble, the Emmy-winning series was not supported by many of its stars at the event held at Los Angeles' Mann 6 Theatre.
The 'Mad Men' star would give voice to an FBI agent who 'has no patience' for Homer in an episode airing this Fall.
Ryan Murphy is 'tickled pink' by 'Glee' 19 nominations while Tina Fey jokes that NBC forgets to cancel '30 Rock' for the fifth time.
The likes of Leah Michelle and Matthew Morrison have helped the musical show to nab nominations in five separate categories.
This year's Primetime Emmy Awards was kicked off with a performance from the host who greeted several celebities sitting as audience.
A few of the first announced presenters group, the actors are joined on the list by Stephen Moyer, Blake Lively, Kiefer Sutherland and more.