#4
Maxwell Smart and Agent 99 in 'Get Smart'
This unlikely duo is the only different-sex pair in this list. But, it doesn't stop them from raising eyebrows when they work together. An analyst for intelligence agency CONTROL, Maxwell (Steve Carell) has no competence to be a spy. He is bumbling, ambitious and unreasonably full of confidence. On the other hand, beautiful Agent 99 (Anne Hathaway) has known the business for a long time and an expert in her work. If the security of CONTROL headquarters had not been breached by its arch-enemy KAOS, these two won't even have the chance to save the world together. Still, for most of the time, it is Agent 99 who ends up saving Max for his ticklish actions.
