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The on- and off- screen couple came together to the Village Theatre in Westwood, California where they were joined by co-stars Teresa Palmer and Callan McAuliffe.
Number Four's true identity almost revealed itself during a night swimming but he exposes himself in front of a girl who captures his heart.
There are more scenes showing how alien teen Number Four builds relationship with a girl and learns to control his special power.
Beside the smooching scenes, the new sneak peek video also shares how Pettyfer's John Smith learns about his power and uses it to help his love interest.
An alien teen on the run from ruthless enemies sent to destroy him, Pettyfer's John Smith is learning his powerful new abilities when trying to survive from a deadly enemy.
'He's not hard to look at but..., it's still a little awkward,' the star says on the scene that was filmed first for the movie.
Number Four is the next one who is going to be hunted after three of nine alien teens escaping from their planet have been killed by their enemies.
The depicter of Quinn Fabray in the TV series nabs the female lead in the action sci-fi movie which is produced by Michael Bay and Steven Spielberg.