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'Clouds of Sils Maria', 'Foxcatcher', 'Maps to the Stars', 'Mr. Turner', 'Whiplash' and 'Pasolini' are among the selections for the annual event.
The 'Kick-Ass' actress channels her inner troublemaker as a young Hollywood actress with a penchant for scandal.
Stewart and Moretz are joined fellow cast member Juliette Binoche, while Thurman comes with 'Pulp Fiction' crew like John Travolta and Quentin Tarantino.
The first trailer from Olivier Assayas reveals Stewart as an aging actress' personal assistant as well as object of desire.
Robert Pattinson's film will compete for the coveted Palme d'Or prize along with Kristen Stewart's movie and Channing Tatum's flick which also stars Steve Carell.
The two lead stars of the forthcoming film take off their clothes to film a risque scene set in the Swiss mountains.