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Baccarin will portray Ryan Reynolds' love interest who 'grapples with falling for a man with a hideously scarred face.'
Crystal Reed, Rebecca Rittenhouse, Sarah Greene, and Jessica De Gouw are also lined up as contenders to play the leading lady in the Ryan Reynolds-starring superhero flick.
The actress, who also starred on 'Firefly', is cast as DC Comics character Dr. Leslie Thompkins.
The actress gave birth to her and husband Austin Chick's first child, Julius, on Tuesday via breech delivery.
Baccarin and her husband Austin Chick are going to be parents for the first time after tying the knot in November 2011.
Bravo, which is looking forward to fill the gap left by Kim Richards and Camille Grammer, has approached Sylvester Stallone's wife, Eddie Cibrian's ex and a Lakers executive.
Captain America holds his shield despite the flying dirt in the new teaser poster that mentions 'avenge'.
Along with Jessica Lucas and Cobie Smulders, the 'V' star and the 'Scott Pilgrim' actress are said to join screen test for the role of Nick Fury's sidekick.