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Sandra Bullock also showed off some singing skills, delivering a few bars of Deep Purple's 'Smoke on the Water' before introducing Faith Hill's performance.
The two female country music singers receive three nominations each along with Jason Aldean and Lady Antebellum.
Lady Antebellum, Jason Aldean and Sugarland have landed four nods apiece at the upcoming CMT Music Awards which will be aired on June 9.
Lady Antebellum, Reba McEntire, Tim McGraw and duo Brooks and Dunn are also booked to make live performances at the April 18 awards show.