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The Jodie Foster-directed film will see West starring alongside the likes of George Clooney, Julia Roberts and Jack O'Connell.
In Michael Grandage's feature debut, Pearce takes the role of F. Scott Fitzgerald while West is set to star as Ernest Hemmingway.
Meanwhile, ITV1's 'Downton Abbey' which also airs on PBS only has one chance to win this year through supporting actress Maggie Smith.
The 'Wire' actor is set to portray Fred West on 'Appropriate Adult', joined by Emily Watson and Monica Dolan.
After exchanging vows on June 26, Dominic West and Catherine Fitzgerald were back in church the next day to christen their three young children.
The two stars, along with Sadie Frost, Jaime Winstone and Samantha Morton, have made their own illustrations of the big wheel to raise money to benefit the Evelina Children's Hospital.
After proposing Catherine Fitzgerald in 2007, Dominic West will finally exchange wedding vows with her later this month.