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She previously described her late husband Jason Rae as 'irreplaceable' but the singer eventually opens her heart for a long-term friend Steve Brown.
Dizzee Rascal, Laura Marling, Mumford & Sons and The xx will also battle it out for the coveted prize, which will be presented at a ceremony in London on September 7.
The Adria Petty-directed music video gives 'a dreamy sensuous feel' which perfectly fits the feel of the song.
Kate Nash, Stella McCartney, Samantha Morton and Dame Vivienne Westwood have also lent their support for this women campaign.
Following the death of her husband Jason Rae, Corinne Bailey Rae admits that she finds it hard to live alone in her marital home but decided to live there since Leeds will always be her base.