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The British beauty plays a rebellious student who hijacks a school bus, takes a trip to a lingerie store and angers Rose McGowan's chaperone at a prom.
The British singer says the punk/rock track is inspired by lots of things she listened to while making a punk album in Sweden.
The British singer, whose collaborations with Iggy Azalea and Icona Pop have topped the charts, says that working with the former Disney star is not 'right.'
The video, which was shot in Amsterdam, features some scenes from the upcoming movie which will open in the U.S. on June 6.
Sheeran performs 'All of the Stars' while Charli sings 'Boom Clap' at the event which also features interview with the movie's stars including Shailene Woodley and Ansel Elgort.
The clip, which features the Australian femcee and the British singer redoing some scenes from 'Clueless', was filmed at the same high school where the 1995 film was shot.