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The Nickelodeon star says the song is special to her because it's one of the first songs she did when she started working on her first album, 'Yours Truly'.
The Ryan Seacrest-hosted concert also features performances by Ed Sheeran, Calvin Harris, Shakira, and Maroon 5.
In one of the photos shared on Instagram, the Nickelodeon star is seen donning a super mini outfit and a pair of white boots while sitting on a motorcycle.
The 'Problem' singer is seen smooching her former beau and showing off PDA backstage at Los Angeles' Shrine Auditorium.
After Bieber congratulates Grande on her chart-topping new single and posts a photo of them hanging out in a studio together, the Nickelodeon star says, 'Secrets out now.'
The hit single, which has topped iTunes charts since its release earlier this week, is predicted to make its debut in the top 10 on Billboard 100 next week.
The annual awards-giving show also features performances from other artists including Austin Mahone, Fifth Harmony and Zendaya Coleman.
The preview features Azalea rapping the verses she has recorded for the song that's scheduled to be debuted in full on April 27.
The singer takes to Instagram to preview 'a little part from the lyric video' because the music video hasn't been shot yet.
The Nickelodeon star will perform the new single when she takes the stage at Radio Disney Music Awards later this month.
The Nickelodeon star has said on Twitter that she'll play the new single during her performance at the Palm Spring's White Party on April 26.
The teaser clip shows the 'Fine China' singer dancing alone in a dimly-lit room as a portion of the song is being played in the background.
Grande denies that Jennette McCurdy's feud with Nickelodeon is caused by money issue, claiming that she and her co-star receive an equal salary.
One Direction and Jennifer Lawrence won the most nods at the awards show while producer Dan Schneider received the show's first lifetime award ever.
Michele stole the attention upon her arrival with her peach minidress while Cuoco failed to rack up nods for her unflattering ensemble.